Ring Inversion in Substituted Spiro[2.5]octanes.
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چکیده
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Restricted rotation of the amino group and ring inversion in substituted thienopyridines. A dynamic NMR and quantum mechanical study
A series of sixand eight-membered ring-fused aminothiophenes 1-8 was investigated in terms of the height of the rotational barrier of the amino group by dynamic H NMR spectroscopy and quantum chemical methods. The restricted rotation around the N-C(sp) bond depends only on steric influences of the fused ring. The compounds with the eight-membered fused ring show a decreased barrier to rotation....
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1973
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.27-1460